Barrier Metal DPT Material Electrode Material Etch Hard Mask Filem GST Material Gap Fill Material High-k for Capacitor High-k for Metal Gate Low-k Metallization Metal SiO2 / SiN Metal deposition process has been changed from PVD(Physical Vapor Deposition) to CVD(Chemical Vapor Deposition)/ALD(Atomic Layer Deposition) because of scaling down on semiconductor device. It makes metal precursors be changed either. Alpis-3 and MABOC are CVD/ALD metal precursors developed by DNF following roadmap. ※ Metallization Metal Materials change : W(Resistivity 8.0 μΩ-cm) → Al(2.7 μΩ-cm) → Cu(1.7 μΩ-cm) ※ Metal Deposition process change : PVD → CVD → ALD PRODUCT (Cp)Co(CO)2 (cyclopentadienyl)(dicarbonyl)cobalt 자세히보기 Alpis-3 Aluminum borohydride trimethylamine 자세히보기 BTBBDMT (= TBDMW) Bis(t-butylimido)bis(dimethylamido)Tungsten 자세히보기 CCTBA (Hexacarbonyl)(t-butylacetylene)dicobalt 자세히보기 DMAH Dimethylalane 자세히보기 DMEAA Dimethylethylamine:alane 자세히보기 MABONi [= Ni(dmamb)2] (1-dimethylamino-2-methyl-2-butoxide)Nickel(II) 자세히보기 Ni(EtCp)2 Bis(ethylcyclopentadienyl) Nickel 자세히보기 TMA Trimethylaluminium 자세히보기 (Cp)Co(CO)2 Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. (cyclopentadienyl)(dicarbonyl)cobalt Chemical formula C7H5CoO2 formula weight (g/mol) 180.11 Boiling point (℃) 177 Vapor pressure (℃/torr) 20 / 0.92 Phase Orange liquid Water reactivity Slowly react 닫기 Alpis-3 Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. Aluminum borohydride trimethylamine Chemical formula C3H15AlBN formula weight (g/mol) 102.95 Boiling point (℃) 195 Vapor pressure (℃/torr) 40 / 1.0 Phase Colorless liquid Water reactivity Violently react 닫기 BTBBDMT (= TBDMW) Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. Bis(t-butylimido)bis(dimethylamido)Tungsten Chemical formula C2H30N4W formula weight (g/mol) 414.23 Boiling point (℃) 60 / 0.05 Vapor pressure (℃/torr) 40 / 0.1 Phase Pale yellow liquid Water reactivity Slowly react 닫기 CCTBA Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. (Hexacarbonyl)(t-butylacetylene)dicobalt Chemical formula C12H10O6Co2 formula weight (g/mol) 368.07 Boiling point (℃) 52 / 0.8 Vapor pressure (℃/torr) 40 / 0.1 Phase Reddish brown liquid Water reactivity No reaction 닫기 DMAH Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. Dimethylalane Chemical formula C2H7Al formula weight (g/mol) 58.06 Boiling point (℃) 154 Vapor pressure (℃/torr) 25 / 1.9 Phase Colorless liquid Water reactivity Violently react 닫기 DMEAA Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. Dimethylethylamine:alane Chemical formula C4H14AlN formula weight (g/mol) 103.14 Boiling point (℃) 50 / 0.05 Vapor pressure (℃/torr) 24 / 1.98 Phase Colorless liquid Water reactivity Violently react 닫기 MABONi [= Ni(dmamb)2] Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. (1-dimethylamino-2-methyl-2-butoxide)Nickel(II) Chemical formula C14H32N2O2Ni formula weight (g/mol) 319.19 Boiling point (℃) 148 / 3.32 Vapor pressure (℃/torr) 80 / 0.1 Phase Dark green liquid Water reactivity Slowly react 닫기 Ni(EtCp)2 Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. Bis(ethylcyclopentadienyl) Nickel Chemical formula C14H18Ni formula weight (g/mol) 244.99 Boiling point (℃) 90 / 0.05 Vapor pressure (℃/torr) 85 / 0.2 Phase Green liquid Water reactivity Slowly react 닫기 TMA Chemical name, Chemical formula, formula weight (g/mol), Boiling point (℃), Vapor pressure (℃/torr), Phase, Water reactivity Chemical name. Trimethylaluminium Chemical formula C6H18Al2 formula weight (g/mol) 144.18 Boiling point (℃) 125 Vapor pressure (℃/torr) 60 / 69.3 Phase Colorless liquid Water reactivity Violently react 닫기